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Pesticide exposure assessment for surface waters in the EU
(2016) Bach, Martin; Diesner, Mirjam; Großmann, Dietlinde; Müller, Alexander; Priegnitz, Jan
In 2001, the European Commission introduced a risk assessment project known as FOCUS (FOrum for the Coordination of pesticide fate models and their USe) for the surface water risk assessment of active substances in the European Union. Even for the national authorisation of plant protection products (PPPs), the vast majority of EU member states still refer to the four runoff and six drainage scenarios selected by the FOCUS Surface Water Workgroup. However, our study, as well as the European Food Safety Authority (EFSA), has stated the need for various improvements. Current developments in pesticide exposure assessment mainly relate to two processes. Firstly, predicted environmental concentrations (PECs) of pesticides are calculated by introducing model input variables such as weather conditions, soil properties and substance fate parameters that have a probabilistic nature. Secondly, spatially distributed PECs for soilŃclimate scenarios are derived on the basis of an analysis of geodata. Such approaches facilitate the calculation of a spatiotemporal cumulative distribution function (CDF) of PECs for a given area of interest and are subsequently used to determine an exposure concentration endpoint as a given percentile of the CDF. For national PPP authorisation, we propose that, in the future, exposure endpoints should be determined from the overall known statistical PEC population for an area of interest, and derived for soil and climate conditions specific to the particular member state. © 2016 Society of Chemical Industry
Calculation of a food consumption nitrogen footprint for Germany
(2021) Klement, Laura; Bach, Martin; Geupel, Markus
Reactive nitrogen (Nr) that is released to the environment has several negative implications for the atmosphere, hydrosphere, biodiversity and human health. A nitrogen (N) footprint is a measure that can help to assess and communicate the impact of personal lifestyle and consumption choices regarding their influences on Nr losses. The N-Calculator tool was developed to estimate this footprint. However, underlying loss factors for the food sector in the N-Calculator rely on data from the US, for which the calculator was originally established. Since the conditions in agriculture and the food industry differ significantly between the US and other countries, and the fact that the food sector is considered the main source of Nr losses in the N-Calculator, a revision of the N-Calculator is required if applied to other countries. Here we present a revised N-Calculator for Germany that is based on German food production data. In this study, virtual nitrogen factors describe the losses of nitrogen in a supply chain. Losses were calculated for 20 plant-based products, 17 feed materials, 18 compound feeds and 14 animal-based products. The N footprint varies considerably between products. While plant-based products amount to a weighted average of 3.4 g N loss per kg product, animal-based products cause significantly higher losses with 40.5 g N loss per kg. Overall, the average N footprint for the German consumer is calculated to be at 9.94 kg per capita and year. To validate the results, the individual categories were scaled up to the national level and then compared with statistical data on N flows in Germany. In general, the results showed good agreement with key production figures and the overall N budget for Germany. Furthermore, some improvements are proposed to increase the informative value and user acceptance of an N-Calculator. © 2021 The Author(s)
National nitrogen budget for Germany
(2021) Häußermann, Uwe; Bach, Martin; Fuchs, Stephan; Geupel, Markus
Emissions of reactive nitrogen (Nr) give rise to a wide range of environmental problems. Nitrogen budgets for various systems and on different scales are an established tool to quantify the sources and fate of Nr. The national nitrogen budget (NNB) for Germany calculates the nitrogen flows for eight pools: Atmosphere, Energy and Fuels, Material and Products in Industry, Humans and Settlements, Agriculture, Forest and Semi-natural Vegetation, Waste, and Hydrosphere, as well as for the transboundary N-flows. In Germany, in total 6,275 kt Nr a-1 has been introduced into the nitrogen cycle annually (mean 2010 to 2014), of which 43% stem from ammonia synthesis. Domestic extraction and import of nitrogenous fossil fuels (lignite, coal, crude oil) releases another 2,335 kt Nr a-1. Import of food, feed and materials contributes 745 kt Nr a-1, while biological N fixation converts 308 kt Nr a-1 into organically bound nitrogen. In terms of Nr sinks, the combustion and denoxing of fuels and the refining of crude oil converts 2,594 kt Nr a-1 to N2. In waters, soils, and wastewater treatment plants, denitrification leads to the release of 1,107 kt Nr a-1 as N2. Via the atmosphere and hydrosphere, Germany exports 755 kt Nr a-1 to neighbouring countries and into coastal waters. On balance, Germany releases 1,627 kt Nr a-1 annually to the environment. However, the NNB as a whole and the individual pool balances involve substantial uncertainties, which have to be considered when interpreting the results. ©2021 The Author(s)

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