Person: Janzen, Wolfgang
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Veröffentlichung Scientific guidance on soil phototransformation products in groundwater - consideration, parameterisation and simulation in the exposure assessment of plant protection products(2022) Schneider, Franziska; Janzen, Wolfgang; Jentzsch, Franziska; Egsmose, Mark; Pickl, Christina; Fait, Gabriella; Priegnitz, JanThis Guidance Document gives recommendations how to consider transformation products from soilphotolysis (â€Ìphototransformation productsâ€Ì) when modelling the predicted environmental concentrationsin groundwater. It describes possible parameterisations of the photolytic pathway (i.e. the photolytic half-life and the corresponding reference irradiation) in a tiered approach using the FOCUS-PELMO model.Following the recommendations of the EFSA guidance (2014), separate half-lives can be derived for thesurface processes (kfast) and the biodegradation in the soil matrix (kslow) fromfield dissipation studies byusing biphasic models. Fromfield dissipation studies evaluated with biphasic kinetics, the kfastvalue canbe considered representative for the photolytic degradation on soil surface for non-volatile substances.This value should be determined after a time-step normalisation according to irradiance data for thelocation and period of thefield trial, to a reference irradiance of 100 W mâ Ì2. In case irradiance values arenot available in the study, these values can be derived from databases such as AGRI4CAST or NASA,freely available in the Internet. Quelle: Artikel